The most attractive peg-wood may depend on the fingerboard wood, and that may depend in part on the wood choice for back and sides. I generally tend to prefer Ebony fingerboards, although light woods also can be attractive, depending on the woods used for the rest of a guitar. The Tsiorba guitar in this video is a blanca, rather than a negra, but it is an example of light fingerboard that I like:
Of course, other considerations beyond peg appearance are functionality and wearing characteristics. Bearing surfaces tend to work more smoothly without binding if dissimilar materials are used, which, of course, is why brass and steel are commonly used for metal bearing surfaces instead of steel and steel or brass and brass. So, it seems that for smooth long-term peg functionality with minimal wear the peg and head woods should have significantly different grain structures and hardness.
-Bob
